Friday, July 10, 2009

Macromolecules 2009, 42, 3761-3766

Efficient Synthesis of Narrowly Dispersed Brush Polymers via Living Ring-Opening Metathesis Polymerization of Macromonomers

Yan Xia, Julia A. Kornfield, and Robert H. Grubbs*
Arnold and Mabel Beckman Laboratory of Chemical Synthesis, DiVision of Chemistry and Chemical
Engineering, California Institute of Technology, Pasadena, California 91125

Macromolecules 2009, 42, 4127–4133

Thiol-functionalized ROMP polymers via Sacrificial Synthesis

Stefan Hilf and Andreas F. M. Kilbinger*
Institut fur Organische Chemie, Johannes Gutenberg-University at Mainz, Duesbergweg 10-14, D-55099 Mainz, Germany

Macromolecules 2009, 42, 4023–4027

ROMP from ROMP: A New Approach to Graft Copolymer Synthesis

Matthew J. Allen,†,§ Kittikhun Wangkanont,† Ronald T. Raines,†,‡ and Laura L. Kiessling*,†,‡
†Department of Chemistry and ‡Department of Biochemistry, University of Wisconsin;Madison, Madison,
Wisconsin 53706. §Present address: Department of Chemistry, Wayne State University, Detroit, MI 48202

Wednesday, July 8, 2009

Soft Matter, 2009, 5, 2347–2351

Temperature and redox responsive hydrogels from ABA triblock copolymers prepared by RAFT polymerization

Andrew P. Vogt and Brent S. Sumerlin*

Soft Matter, 2009, 5, 2648–2657

Smart hydrogels based on double responsive triblock terpolymers

Stefan Reinicke,a Joachim Schmelz,a Alain Lapp,b Matthias Karg,c Thomas Hellwegc and Holger Schmalz


Angew. Chem. Int. Ed. 2009, 48, 4589 –4593

Multicompartmental Microcylinders
Srijanani Bhaskar, Jonathon Hitt, Sei-Won Laura Chang, and Joerg Lahann*

Angew. Chem. Int. Ed. 2009, 48, 4508 –4512

A Supramolecularly Assisted Transformation of Block Copolymer Micelles into Nanotubes
Sung Ho Kim, Fredrik Nederberg, Robert Jakobs, Jeremy P. K. Tan, Kazuki Fukushima, Alshakim Nelson, E. W. Meijer, Yi Yan Yang, and James L. Hedrick*

Angew. Chem. Int. Ed. 2009, 48, 5125 –5128

Suprapolymer Structures from Nanostructured Polymer Particles
Takeshi Higuchi,* Atsunori Tajima, Kiwamu Motoyoshi, Hiroshi Yabu,* and Masatsugu Shimomura

Angew. Chem. Int. Ed. 2009, 48, 5170 –5173

Hydrogen-Bonding Catalysts Based on Fluorinated Alcohol Derivatives for Living Polymerization
Olivier Coulembier,Daniel P. Sanders,Alshakim Nelson, Andrew N. Hollenbeck, Hans W. Horn, Julia E. Rice, Masaki Fujiwara, Philippe Dubois, and James L. Hedrick*

Nano Letters, Vol. 9, No. 6

Block Copolymer Nanostructures Mapped by Far-Field Optics

Chaitanya K. Ullal, Roman Schmidt, Stefan W. Hell and Alexander Egner

pp 2497–2500

Bioconjugate Chem. 2009, 20, 1100–1111

Lamellarin D Bioconjugates I: Synthesis and Cellular Internalization of
PEG-Derivatives


Daniel Pla,†,‡ Andre´s Francesch,§ Pilar Calvo,§ Carmen Cuevas,§ Rosa Aligue´, Fernando Albericio,*,⊥,†,‡ and Mercedes A´ lvarez*,#,

Improving Grubbs’ II type ruthenium catalysts by appropriately modifying the N-heterocyclic carbene ligand

Ludovic Vieille-Petit, Xinjun Luan, Michele Gatti, Sascha Blumentritt, Anthony Linden, Herve´ Clavier, Steven P. Nolanb and Reto Dorta
Chem. Commun., 2009, 3783–3785

Monday, July 6, 2009

Antibacterial cyclic D,L-a-glycopeptides

Leila Motiei, Shai Rahimipour, Desiree A. Thayer, Chi-Huey Wong and M. Reza Ghadiri
Chem. Commun., 2009, 3693–3695

Gold nanoring arrays from responsive block copolymer templates

Li Wang, Franck Montagne, Patrik Hoffmannb and Raphael Pugina
Chem. Commun., 2009, 3798–3800

Adv. Funct. Mater. 2009,19, 1–8

Spontaneous Lamellar Alignment in Thickness-Modulated Block Copolymer Films
Hoon Kim, Hyung Min Lee, Joo-Hyung Lee, Seung-Woo Son, Seong-Jun Jeong, Sumi Lee, Dong Il Lee, Sin Ung Kwak, Hawoong Jeong, Hyunjung Shin, Jun-Bo Yoon, Oleg D. Lavrentovich, and Sang Ouk Kim


ACS Nano, 2009, 3 (6), pp 1423–1430

Polymer-Assisted Direct Deposition of Uniform Carbon Nanotube Bundle Networks for High Performance Transparent Electrodes

Abstract:

Flexible transparent electrodes are crucial for touch screen, flat panel display, and solar cell technologies. While carbon nanotube network electrodes show promise, characteristically poor dispersion properties have limited their practicality. We report that addition of small amounts of conjugated polymer to nanotube dispersions enables straightforward fabrication of uniform network electrodes by spin-coating and simultaneous tuning of parameters such as bundle size and density. After treatment in thionyl chloride, electrodes have sheet resistances competitive with other reported carbon nanotube based transparent electrodes to date.

ACS Nano, 2009, 3 (6), pp 1335–1344

Homogeneous Conjugation of Peptides onto Gold Nanoparticles Enhances Macrophage Response

Abstract:

Murine bone marrow macrophages were able to recognize gold nanoparticle peptide conjugates, while peptides or nanoparticles alone were not recognized. Consequently, in the presence of conjugates, macrophage proliferation was stopped and pro-inflammatory cytokines such as TNF-α, IL-1β, and IL-6, as well as nitric oxide synthase (NOS2) were induced. Furthermore, macrophage activation by gold nanoparticles conjugated to different peptides appeared to be rather independent of peptide length and polarity, but dependent on peptide pattern at the nanoparticle surface. Correspondingly, the biochemical type of response also depended on the type of conjugated peptide and could be correlated with the degree of ordering in the peptide coating. These findings help to illustrate the basic requirements involved in medical nanoparticle conjugate design to either activate the immune system or hide from it in order to reach their targets before being removed by phagocytes.

Friday, July 3, 2009

Org. Biomol. Chem., 2009, 7, 2855

Porphyrin-linked nitroimidazole antibiotics targeting Porphyromonas gingivalis
Benjamin C.-M. Yap, Grace L. Simpkins, Charles A. Collyer, Neil Hunter and Maxwell J. Crossley

JACS, 131, 8720-9132, 2009

Fluorescein Redirects a Ruthenium−Octaarginine Conjugate to the Nucleus
Cindy A. Puckett and Jacqueline K. Barton
pp 8738–8739

A Biomimetic Modular Polymer with Tough and Adaptive Properties
Aaron M. Kushner, John D. Vossler, Gregory A. Williams and Zhibin Guan
pp 8766–8768

JACS, 131, 9134-9466, 2009

Liquid-Phase Synthesis of Block Copolymers Containing Sequence-Ordered Segments
Sebastian Pfeifer, Zoya Zarafshani, Nezha Badi and Jean-Franois Lutz
pp 9195–9197

Localized and Sustained Delivery of Silencing RNA from Macroscopic Biopolymer Hydrogels
Melissa D. Krebs, Oju Jeon and Eben Alsberg
pp 9204–9206

From Synthesis to Biologics: Preclinical Data on a Chemistry Derived Anticancer Vaccine
Jianglong Zhu, Qian Wan, Dongjoo Lee, Guangbin Yang, Maria K. Spassova, Ouathek Ouerfelli, Govind Ragupathi, Payal Damani, Philip O. Livingston and Samuel J. Danishefsky
pp 9298–9303

Biomacromolecules, Vol 10, Iss 6 (June 09)

Temperature-Induced Intracellular Uptake of Thermoresponsive Polymeric Micelles
Jun Akimoto, Masamichi Nakayama, Kiyotaka Sakai and Teruo Okano
pp 1331–1336

Chemical Structure of Cationic Groups in Amphiphilic Polymethacrylates Modulates the Antimicrobial and Hemolytic Activities
Edmund F. Palermo and Kenichi Kuroda
pp 1416–1428

Non-cytotoxic Silver Nanoparticle-Polysaccharide Nanocomposites with Antimicrobial Activity
Andrea Travan, Chiara Pelillo, Ivan Donati, Eleonora Marsich, Monica Benincasa, Tommaso Scarpa, Sabrina Semeraro, Gianluca Turco, Renato Gennaro and Sergio Paoletti
pp 1429–1435

Assessment of Antibacterial Properties of Polyvinylamine (PVAm) with Different Charge Densities and Hydrophobic Modifications
Eva-Helena Westman, Monica Ek, Lars-Erik Enarsson and Lars Wågberg
pp 1478–1483