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Thursday, December 27, 2007
Chem Rev. Vol. 107, No. 12, (Dec 2007)
.
Asymmetric Catalysis Mediated by Synthetic Peptides
Elizabeth A. Colby Davie, Steven M. Mennen, Yingju Xu, and Scott J. Miller
pp 5759 - 5812
Organocatalytic Ring-Opening Polymerization
Nahrain E. Kamber, Wonhee Jeong, Robert M. Waymouth, Russell C. Pratt, Bas G. G. Lohmeijer, and James L. Hedrick
pp 5813 - 5840
Asymmetric Catalysis Mediated by Synthetic Peptides
Elizabeth A. Colby Davie, Steven M. Mennen, Yingju Xu, and Scott J. Miller
pp 5759 - 5812
Organocatalytic Ring-Opening Polymerization
Nahrain E. Kamber, Wonhee Jeong, Robert M. Waymouth, Russell C. Pratt, Bas G. G. Lohmeijer, and James L. Hedrick
pp 5813 - 5840
JACS Vol. 129, No. 49, (Dec 12, 2007)
.
Polymer-Caged Lipsomes: A pH-Responsive Delivery System with High Stability
Sang-Min Lee, Haimei Chen, Christine M. Dettmer, Thomas V. O'Halloran, and SonBinh T. Nguyen
pp 15096 - 1509
Considerations of Macromolecular Structure in the Design of Proton Conducting Polymer Membranes: Graft versus Diblock Polyelectrolytes
Emily M. W. Tsang, Zhaobin Zhang, Zhiqing Shi, Tatyana Soboleva, and Steven Holdcroft
pp 15106 - 15107
Site-Directed Conjugation of "Clicked" Glycopolymers To Form Glycoprotein Mimics: Binding to Mammalian Lectin and Induction of Immunological Function
Jin Geng, Giuseppe Mantovani, Lei Tao, Julien Nicolas, Gaojian Chen, Russell Wallis, Daniel A. Mitchell, Benjamin R. G. Johnson, Stephen D. Evans, and David M. Haddleton
pp 15156 - 15163
Polymer-Caged Lipsomes: A pH-Responsive Delivery System with High Stability
Sang-Min Lee, Haimei Chen, Christine M. Dettmer, Thomas V. O'Halloran, and SonBinh T. Nguyen
pp 15096 - 1509
Considerations of Macromolecular Structure in the Design of Proton Conducting Polymer Membranes: Graft versus Diblock Polyelectrolytes
Emily M. W. Tsang, Zhaobin Zhang, Zhiqing Shi, Tatyana Soboleva, and Steven Holdcroft
pp 15106 - 15107
Site-Directed Conjugation of "Clicked" Glycopolymers To Form Glycoprotein Mimics: Binding to Mammalian Lectin and Induction of Immunological Function
Jin Geng, Giuseppe Mantovani, Lei Tao, Julien Nicolas, Gaojian Chen, Russell Wallis, Daniel A. Mitchell, Benjamin R. G. Johnson, Stephen D. Evans, and David M. Haddleton
pp 15156 - 15163
JACS Vol. 129, No. 48, (Dec 5, 2007)
.
Protonation States of Buried Histidine Residues in Human Deoxyhemoglobin Revealed by Neutron Crystallography
Toshiyuki Chatake, Naoya Shibayama, Sam-Yong Park, Kazuo Kurihara, Taro Tamada, Ichiro Tanaka, Nobuo Niimura, Ryota Kuroki, and Yukio Morimoto
pp 14840 - 14841
Misfolding of Amyloidogenic Proteins at Membrane Surfaces: The Impact of Macromolecular Crowding
Marcus Bokvist and Gerhard Gröbner
pp 14848 - 14849
Total Synthesis and Antibacterial Properties of Carbaplatensimycin
K. C. Nicolaou, Yefeng Tang, Jianhua Wang, Antonia F. Stepan, Ang Li, and Ana Montero
pp 14850 - 14851
Anticancer and Antimicrobial Metallopharmaceutical Agents Based on Palladium, Gold, and Silver N-Heterocyclic Carbene Complexes
Sriparna Ray, Renu Mohan, Jay K. Singh, Manoja K. Samantaray, Mobin M. Shaikh, Dulal Panda, and Prasenjit Ghosh
pp 15042 - 15053
Protonation States of Buried Histidine Residues in Human Deoxyhemoglobin Revealed by Neutron Crystallography
Toshiyuki Chatake, Naoya Shibayama, Sam-Yong Park, Kazuo Kurihara, Taro Tamada, Ichiro Tanaka, Nobuo Niimura, Ryota Kuroki, and Yukio Morimoto
pp 14840 - 14841
Misfolding of Amyloidogenic Proteins at Membrane Surfaces: The Impact of Macromolecular Crowding
Marcus Bokvist and Gerhard Gröbner
pp 14848 - 14849
Total Synthesis and Antibacterial Properties of Carbaplatensimycin
K. C. Nicolaou, Yefeng Tang, Jianhua Wang, Antonia F. Stepan, Ang Li, and Ana Montero
pp 14850 - 14851
Anticancer and Antimicrobial Metallopharmaceutical Agents Based on Palladium, Gold, and Silver N-Heterocyclic Carbene Complexes
Sriparna Ray, Renu Mohan, Jay K. Singh, Manoja K. Samantaray, Mobin M. Shaikh, Dulal Panda, and Prasenjit Ghosh
pp 15042 - 15053
Monday, December 17, 2007
Science, VOL 318, ISSUE 5857, PAGES 1691-1793, 14 December 2007
RESEARCH POLICY: NIH Weighs Big Changes in Peer Review
Jennifer Couzin
pg. 1708-1709.
NASA Funding Slow, Not Steady, After Space Race
Michael J. Goldstein
pg. 1721-1722
Jennifer Couzin
pg. 1708-1709.
NASA Funding Slow, Not Steady, After Space Race
Michael J. Goldstein
pg. 1721-1722
Tuesday, December 11, 2007
Biomaterials, Volume 29, Issue 6, Pages 625-770 (February 2008)
The use of biodegradable scaffold as an alternative to silicone implant arthroplasty for small joint reconstruction: An experimental study in minipigs
Pages 683-691
Eero Waris, Nureddin Ashammakhi, Mauri Lehtimäki, Riitta-Mari Tulamo, Minna Kellomäki, Pertti Törmälä and Yrjö T. Konttinen
Luminescence functionalization of mesoporous silica with different morphologies and applications as drug delivery systems
Pages 692-702
Piaoping Yang, Zewei Quan, Lanlan Lu, Shanshan Huang and Jun Lin
Pages 683-691
Eero Waris, Nureddin Ashammakhi, Mauri Lehtimäki, Riitta-Mari Tulamo, Minna Kellomäki, Pertti Törmälä and Yrjö T. Konttinen
Luminescence functionalization of mesoporous silica with different morphologies and applications as drug delivery systems
Pages 692-702
Piaoping Yang, Zewei Quan, Lanlan Lu, Shanshan Huang and Jun Lin
Science, Vol 318, Issue 5856, pages 1519-1648, 7 DECEMBER 2007
Editorial
Chinese Science on the Move
A. I. Leshner, and V. Turekian
pg. 5856
News of the Week
ACADEMIC FREEDOM: Thai Science Agency Clamps Down on Sensitive Research
R. Stone
pg. 5856
Books
FOR YOUNGER READERS: Science Books for Fun and Learning--Some Recommendations from 2007
H. Malcomson, S. Suter, and B. Jasny
pg. 1552-1554
Reports
Designing Superoleophobic Surfaces
A. Tuteja, W. Choi, M. Ma, J. M. Mabry, S. A. Mazzella, G. C. Rutledge, G. H. McKinley, and R. E. Cohen
pg. 1618-1622
Chinese Science on the Move
A. I. Leshner, and V. Turekian
pg. 5856
News of the Week
ACADEMIC FREEDOM: Thai Science Agency Clamps Down on Sensitive Research
R. Stone
pg. 5856
Books
FOR YOUNGER READERS: Science Books for Fun and Learning--Some Recommendations from 2007
H. Malcomson, S. Suter, and B. Jasny
pg. 1552-1554
Reports
Designing Superoleophobic Surfaces
A. Tuteja, W. Choi, M. Ma, J. M. Mabry, S. A. Mazzella, G. C. Rutledge, G. H. McKinley, and R. E. Cohen
pg. 1618-1622
Monday, December 10, 2007
Chemistry - A European Journal, ASAP article
Tuning the Charge Distribution and Photoswitchable Properties of Cobalt-Dioxolene Complexes by Using Molecular Techniques p(NA)
Alessandra Beni, Andrea Dei, Serena Laschi, Mario Rizzitano, Lorenzo Sorace
Chem. Commun., 2007, 5200 - 5202
Heat-set gels and egg-like vesicles using two component gel system based on chiral calix[4]arenes
Jin-Lan Zhou, Xian-Jie Chen and Yan-Song Zheng
Tuesday, December 4, 2007
ChemPhysChem, 2007, Volume 8 Issue 16 , 2367-2372
Embedding Magnetic Nanoparticles into Polysaccharide-Based Hydrogels for
Magnetically Assisted Bioseparation
Yuan-Yuan Liang, Li-Ming Zhang,* Wei Jiang, and Wei Li
University, Guangzhou, China
Magnetically Assisted Bioseparation
Yuan-Yuan Liang, Li-Ming Zhang,* Wei Jiang, and Wei Li
University, Guangzhou, China
Macromolecules 2007, 40, 9084-9093
Codendronized Polymers: Wormlike Molecular Objects with a
Segmented Structure
Xingquan Xiong and Yongming Chen
Shu Feng and Wei Wang
Segmented Structure
Xingquan Xiong and Yongming Chen
Shu Feng and Wei Wang
ChemPhysChem, 2007, Volume 8 Issue 16 , Pages 2290 - 2307
Interrogation of Single Synthetic Polymer Chains and Polysaccharides by AFM-Based Force Spectroscopy
Marina I. Giannotti, G. Julius Vancso,
University of Twente, Netherlands
Marina I. Giannotti, G. Julius Vancso,
University of Twente, Netherlands
Macromolecules 2007, 40, 8855-8860
Synthesis and Structural Characterization of Magnesium Ketiminate
Complexes: Efficient Initiators for the Ring-Opening Polymerization
of L-Lactide
Hui-Yi Tang, Hsuan-Ying Chen, Jui-Hsien Huang, and Chu-Chieh Lin
Complexes: Efficient Initiators for the Ring-Opening Polymerization
of L-Lactide
Hui-Yi Tang, Hsuan-Ying Chen, Jui-Hsien Huang, and Chu-Chieh Lin
Macromolecules 2007, 40, 8830-8832
Solvent-Promoted Self-Healing Epoxy Materials
Mary M. Caruso, David A. Delafuente, Victor Ho,
Nancy R. Sottos, Jeffrey S. Moore and
Scott R. White
Mary M. Caruso, David A. Delafuente, Victor Ho,
Nancy R. Sottos, Jeffrey S. Moore and
Scott R. White
Journal of Physical Chemistry. B, 2007, 111(48), 13491 - 13498
X-ray Absorption Microscopy of Bacterial Surface Protein Layers: X-ray Damage
Andreas Kade, Denis V. Vyalikh, Steffen Danzenbächer, Kurt Kummer, Anja Blüher, Michael Mertig, Alessandra Lanzara, Andreas Scholl, Andrew Doran, and Serguei L. Molodtsov
Institute of Solid State Physics, Dresden UniVersity of Technology, D-01062 Dresden, Germany,
BioNanotechnology and Structure Formation Group, Max Bergmann Center of Biomaterials, Dresden
Andreas Kade, Denis V. Vyalikh, Steffen Danzenbächer, Kurt Kummer, Anja Blüher, Michael Mertig, Alessandra Lanzara, Andreas Scholl, Andrew Doran, and Serguei L. Molodtsov
Institute of Solid State Physics, Dresden UniVersity of Technology, D-01062 Dresden, Germany,
BioNanotechnology and Structure Formation Group, Max Bergmann Center of Biomaterials, Dresden
Monday, December 3, 2007
Biochemistry 2007, 46, 13856-13863
Role of Helix Nucleation in the Kinetics of Binding of Mastoparan X to Phospholipid Bilayers
Jia Tang, Rachel S. Signarvic, William F. DeGrado, and Feng Gai
Jia Tang, Rachel S. Signarvic, William F. DeGrado, and Feng Gai
Cautionary tale from Angew. Chemie
1,7-Diaza[12]annulene Derivatives? 100-Year-Old Pyridinium Salts!
Manfred Christl, Prof. Dr. *
I hate to take someone else's journal, but this is a smackdown of Wagnerian proportions.
Manfred Christl, Prof. Dr. *
I hate to take someone else's journal, but this is a smackdown of Wagnerian proportions.
Acc. Chem. Res. 2007, 40, 1122–1129
Amino Acid Ionic Liquids
HIROYUKI OHNO* AND KENTA FUKUMOTO
The preparation of ionic liquids derived from amino acids, and their properties, are outlined. Since amino acids have both a carboxylic acid residue and an amino group in a single molecule, they can be used as either anions or cations. These groups are also useful in their ability to introduce functional group(s). Twenty different natural amino acids were used as anions, to couple with the 1-ethyl-3-methylimidazolium cation. The salts obtained were all liquid at room temperature. The properties of the resulting ionic liquids (AAILs) depend on the side groups of the amino acids involved. These AAILs, composed of an amino acid with some functional groups such as a hydrogen bonding group, a charged group, or an aromatic ring, had an increased glass transition (or melting) temperature and/or higher viscosity as a result of additional interactions among the ions. Viscosity is reduced and the decomposition temperature of imidazolium-type salts is improved by using the tetrabutylphosphonium cation. The chirality of AAILs was maintained even upon heating to 150 °C after acetylation of the free amino group. The amino group was also modified to introduce a strong acid group so as to form hydrophobic and chiral ionic liquids. Unique phase behavior of the resulting hydrophobic ionic liquids and water mixture is found; the mixture is clearly phase separated at room temperature, but the solubility of water in this IL increases upon cooling, to give a homogeneous solution. This phase change is reversible, and separation occurs again by raising the temperature a few degrees. It is extraordinary for an IL/water mixture to display such behavior with a lower critical solution temperature. Some likely applications are proposed for these amino acid derived ionic liquids.
HIROYUKI OHNO* AND KENTA FUKUMOTO
The preparation of ionic liquids derived from amino acids, and their properties, are outlined. Since amino acids have both a carboxylic acid residue and an amino group in a single molecule, they can be used as either anions or cations. These groups are also useful in their ability to introduce functional group(s). Twenty different natural amino acids were used as anions, to couple with the 1-ethyl-3-methylimidazolium cation. The salts obtained were all liquid at room temperature. The properties of the resulting ionic liquids (AAILs) depend on the side groups of the amino acids involved. These AAILs, composed of an amino acid with some functional groups such as a hydrogen bonding group, a charged group, or an aromatic ring, had an increased glass transition (or melting) temperature and/or higher viscosity as a result of additional interactions among the ions. Viscosity is reduced and the decomposition temperature of imidazolium-type salts is improved by using the tetrabutylphosphonium cation. The chirality of AAILs was maintained even upon heating to 150 °C after acetylation of the free amino group. The amino group was also modified to introduce a strong acid group so as to form hydrophobic and chiral ionic liquids. Unique phase behavior of the resulting hydrophobic ionic liquids and water mixture is found; the mixture is clearly phase separated at room temperature, but the solubility of water in this IL increases upon cooling, to give a homogeneous solution. This phase change is reversible, and separation occurs again by raising the temperature a few degrees. It is extraordinary for an IL/water mixture to display such behavior with a lower critical solution temperature. Some likely applications are proposed for these amino acid derived ionic liquids.
Chem. Commun., 2007, 4602 - 4604.
One-step synthesis of monodisperse water-soluble dual-responsive magnetic nanoparticles
Ian Robinson, Cameron Alexander, Le T. Lu, Le D. Tung, David G. Fernig and Nguyen T. K. Thanh
Nature Chemical Biology 3, 761-762 (2007) doi:10.1038/nchembio.2007.47
Enzymatic catalysis on conducting graphite particles
Kylie A Vincent1, Xiang Li1, Christopher F Blanford1, Natalie A Belsey1, Joel H Weiner2 and Fraser A Armstrong1A new concept for enzyme-catalyzed redox transformations features pairs of electron donor and acceptor enzymes attached to conducting particles. Electrons furnished by oxidation at one enzyme are used at the other. Graphite microparticles modified with hydrogenase and nitrate reductase or fumarate reductase catalyze reductions of nitrate or fumarate (Compound 1) by H2.
Nature Chemical Biology 3, 785-794 (2007) doi:10.1038/nchembio.2007.46
Catalytic generation of N2O3 by the concerted nitrite reductase and anhydrase activity of hemoglobin
Swati Basu, Rozalina Grubina, Jinming Huang, Jeanet Conradie, Zhi Huang, Anne Jeffers, Alice Jiang, Xiaojun He, Ivan Azarov, Ryan Seibert, Atul Mehta, RakeshPatel, Stephen Bruce King, Neil Hogg, Abhik Ghosh, Mark T Gladwin, and Daniel B Kim-Shapiro
Nano Letters, Vol. 7, Iss. 11, November 2007.
Houjin Huang, Erik Pierstorff, Eiji Osawa, and Dean Ho. pp 3305 - 3314.
K. Jensen, J. Weldon, H. Garcia, and A. Zettl. pp 3508 - 3511.
Journal of Polymer Science: Part A: Polymer Chemistry, Vol. 45, Iss. 24, Dec-2007
Novel double hydrophilic block copolymers based on poly(p-hydroxystyrene) derivatives and poly(ethylene oxide)
Grigoris Mountrichas, Stergios Pispas
pp 5790-5799
Grigoris Mountrichas, Stergios Pispas
pp 5790-5799
Biomacromolecules, Vol. 8, Iss. 11, Nov-2007
New Ground for Organic Catalysis: A Ring-Opening Polymerization Approach to Hydrogels
Fredrik Nederberg, Vivian Trang, Russell C. Pratt, Andrew F. Mason, Curtis W. Frank, Robert M. Waymouth, and James L. Hedrick
pp 3294 - 3297
Steric Stabilization of Lipid/Polymer Particle Assemblies by Poly(ethylene glycol)-Lipids
Julie Thevenot, Anne-Lise Troutier, Laurent David, Thierry Delair, and Catherine Ladavière
pp 3651 - 3660
Shape Memory Behavior of Novel (L-Lactide-Glycolide-Trimethylene Carbonate) Terpolymers
Elisa Zini, Mariastella Scandola, Piotr Dobrzynski, Janusz Kasperczyk, and Maciej Bero
pp 3661 - 3667
Fredrik Nederberg, Vivian Trang, Russell C. Pratt, Andrew F. Mason, Curtis W. Frank, Robert M. Waymouth, and James L. Hedrick
pp 3294 - 3297
Steric Stabilization of Lipid/Polymer Particle Assemblies by Poly(ethylene glycol)-Lipids
Julie Thevenot, Anne-Lise Troutier, Laurent David, Thierry Delair, and Catherine Ladavière
pp 3651 - 3660
Shape Memory Behavior of Novel (L-Lactide-Glycolide-Trimethylene Carbonate) Terpolymers
Elisa Zini, Mariastella Scandola, Piotr Dobrzynski, Janusz Kasperczyk, and Maciej Bero
pp 3661 - 3667
organic letters, 2007, 9, 5039
Cu(II)-Selective Green Fluorescence of a Rhodamine-Diacetic Acid Conjugate
Xuan Zhang, Yasuhiro Shiraishi,* and Takayuki Hirai
Xuan Zhang, Yasuhiro Shiraishi,* and Takayuki Hirai
ChemBioChem 2007, 8, 2063 – 2065
Tuning the Membrane Selectivity of Antimicrobial Peptides by Using
Multivalent Design
Zhigang Liu,[a] Anne W. Young,[a] Po Hu,[a]
Amanda J. Rice,[b] Chunhui Zhou,[a] Yingkai Zhang,[a]
and Neville R. Kallenbach*[a]
Multivalent Design
Zhigang Liu,[a] Anne W. Young,[a] Po Hu,[a]
Amanda J. Rice,[b] Chunhui Zhou,[a] Yingkai Zhang,[a]
and Neville R. Kallenbach*[a]
PNAS Nov 2007 Vol 104 No 48
Combined kinetic and thermodynamic analysis of α-helical membrane protein unfolding
Paul Curnow and Paula J. Booth
They're doing these measurements in a micelle system, which is cool I think.
Paul Curnow and Paula J. Booth
They're doing these measurements in a micelle system, which is cool I think.
PNAS Nov 27, 2007 Vol 104 No 48
Effect of flexibility and cis residues in single-moleculeFRET studies of polyproline
Robert B. Best, Kusai A. Merchant, Irina V. Gopich, Benjamin Schuler, Ad Bax, and William A. Eaton
Robert B. Best, Kusai A. Merchant, Irina V. Gopich, Benjamin Schuler, Ad Bax, and William A. Eaton
J. Mater. Chem., 2007, 17, 4508 - 4520
Development and characterization of porous membranes with ‘‘sandwichlike’’
structure based on biocompatible, immiscible polymer blends
Vincenzo Lanzetta,a Paola Laurienzo,*b Giovanni Maglio,a Mario Malinconico,b Pellegrino Mustob and Immacolata Schiattarellaa
structure based on biocompatible, immiscible polymer blends
Vincenzo Lanzetta,a Paola Laurienzo,*b Giovanni Maglio,a Mario Malinconico,b Pellegrino Mustob and Immacolata Schiattarellaa
. Mater. Chem., 2007, 17, 4471 - 4476
Polymer microcapsules as mobile local pH-sensors
Oliver Kreft, Almudena Munoz Javier, Gleb B. Sukhorukovac and Wolfgang J. Parak
Oliver Kreft, Almudena Munoz Javier, Gleb B. Sukhorukovac and Wolfgang J. Parak
Antimicrobial Agents and Chemotherapy, 2007, 51(12), p4518-4520.
RNAIII-Inhibiting Peptide Affects Biofilm Formation in a Rat Model of Staphylococcal Ureteral Stent Infection
Oscar Cirioni, Roberto Ghiselli, Daniele Minardi, Fiorenza Orlando, Federico Mocchegiani, Carmela Silvestri, Giovanni Muzzonigro, Vittorio Saba, Giorgio Scalise, Naomi Balaban, and Andrea Giacometti
Oscar Cirioni, Roberto Ghiselli, Daniele Minardi, Fiorenza Orlando, Federico Mocchegiani, Carmela Silvestri, Giovanni Muzzonigro, Vittorio Saba, Giorgio Scalise, Naomi Balaban, and Andrea Giacometti
J. Mater. Chem., 2007, 17, 4558 - 4562
Assembly of spherical micelles in 2D physical confinements and their replication into mesoporous silica nanorods
Arne Thomas,a Martin Schierhorn,b Yiying Wuc and Galen Stucky
Arne Thomas,a Martin Schierhorn,b Yiying Wuc and Galen Stucky
Antimicrobial Agents and Chemotherapy, 2007, 51(12), p. 4217-4224.
MINIREVIEW
Outbreaks Associated with Contaminated Antiseptics and Disinfectants
David J. Weber, William A. Rutala, and Emily E. Sickbert-Bennett
Outbreaks Associated with Contaminated Antiseptics and Disinfectants
David J. Weber, William A. Rutala, and Emily E. Sickbert-Bennett
J. Mater. Chem., 2007, 17, 4864 - 4871
Water uptake of hydrophilic polymers determined by a thermal gravimetric analyzer with a controlled humidity chamber
Hanneke M. L. Thijs,a C. Remzi Becer,a Carlos Guerrero-Sanchez,a David Fournier,a Richard Hoogenbooma and Ulrich S. Schubert*ab
Hanneke M. L. Thijs,a C. Remzi Becer,a Carlos Guerrero-Sanchez,a David Fournier,a Richard Hoogenbooma and Ulrich S. Schubert*ab
Organic letters, 2007, 9, 4729
Multisignaling Optical-Electrochemical Sensor for Hg2+ Based on a Rhodamine Derivative with a Ferrocene Unit
Hong Yang, Zhiguo Zhou, Kewei Huang, Mengxiao Yu, Fuyou Li,* Tao Yi, and
Chunhui Huang*
Hong Yang, Zhiguo Zhou, Kewei Huang, Mengxiao Yu, Fuyou Li,* Tao Yi, and
Chunhui Huang*
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