Macromolecules, 2010, 43 (9), pp 4113–4119

Reaction Rates and Mechanisms for Radical, Photoinitated Addition of Thiols to Alkynes, and Implications for Thiol−Yne Photopolymerizations and Click Reactions

Benjamin D. Fairbanks†, Evan A. Sims†, Kristi S. Anseth†§ and Christopher N. Bowman*†
† Department of Chemical and Biological Engineering
§ Howard Hughes Medical Institute
University of Colorado, Boulder, Colorado 80309-0424