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Monday, June 9, 2008

New J. Chem., 2008, 32, 790 - 793

Synthesis and structures of luminescent ladder-like lanthanide coordination polymers of 4-hydroxybenzenesulfonate

Xiaoping Yang, Joseph H. Rivers, W. Jeffrey McCarty, Michael Wiester and Richard A. Jones

Reaction of sodium 4-hydroxybenzenesulfonate dihydrate (NaL·2H2O) with LnCl3·6H2O (3 1) in refluxing methanol gives the novel isomorphous 1-D framework compounds {[LnL3(H2O)2]·2H2O} (Ln = Tb, Er and Yb) in 46–60% yields; the structures of the compounds have been determined by X-ray crystallography and their luminescence properties determined.

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